作者：陈影, 谢光远, 徐晓强, 张舟
作者单位：武汉科技大学材料与冶金学院, 湖北 武汉 430081
关键词：NOx传感器;泵电流;工作温度;氧化增重
摘要：
为探究工作温度对ZrO2基NOx传感器泵电流信号影响，优化控制其工作温度，采用单泵法测量不同工作温度下ZrO2基NOx传感器中主泵、辅助泵和测量泵的泵电流，对各泵电流曲线进行分析，并与推导出的温度与泵电流理论关联式比较。实验结果表明，主泵泵电流与温度的关系与理论关系一致，而辅助泵和测量泵泵电流和温度的关系与理论关系有所偏差。辅助泵中扩散通道结构较复杂，使得曲线斜率呈增大趋势；测量泵中活化电极含有Pt、Rh元素，高温下Rh有氧化增重现象，同时考虑基体二氧化锆高温导电性能，使得曲线斜率呈先增大后减小趋势。综合来看，比较合理的工作温度范围为1 003.15~1 063.15 K，从而可以在温控良好的情况下进一步自主研发出具有良好工作性能的NOx传感器。
Test and analysis about effect of operating temperature on pump current of ZrO2-based NOx sensor
CHEN Ying, XIE Guangyuan, XU Xiaoqiang, ZHANG Zhou
School of Materials and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
Abstract: To explore the influence of operating temperature to the pump current signal in ZrO2-based NOx sensor,and to optimize the operating temperature, single-pump method is taken to measure the pump current of main pump, auxiliary pump and measuring pump in ZrO2-based NOx sensor under different operating temperatures, analyze the pump current curve, and compare with the deduced theoretical correlation of temperature and pump current. Experimental result shows that the relationship between the main pump current and temperature is in accordance with the theory, but the relationships between the current of auxiliary pump as well as measuring pump and temperature deviate from the theoretical relationship. The structure of the diffusion channel in the auxiliary pump is more complicated, which makes the slope of the curve increase; The active electrode in the measuring pump contains Pt and Rh elements, there is an oxidized weight gain of Rh at high temperature, and consider the high-temperature conductivity of the matrix zirconia, the slope of the curve increases at first and then decreases.Taken together, a more reasonable operating temperature range is 1 003.15-1 063.15 K, which can be in the case of good temperature control to further develop a good working performance of the NOx sensor.
Keywords: NOx sensor;pump current;operating temperature;oxidation weight gain
2019, 45(2):104-110 收稿日期: 2017-12-25;收到修改稿日期: 2018-02-28
基金项目:
作者简介: 陈影(1995-),女,湖北武汉市人,硕士研究生,专业方向为大型车用NOx传感器
参考文献
[1] 徐景, 龚雪飞, 张帆, 等. 基于氮氧传感器的NOx气体测量仪设计[J]. 传感器与微系统, 2015, 34(3):90-93
[2] 赵海燕, 王岭, 陈嘉庚, 等. 汽车尾气用NOx传感器[J]. 传感器与微系统, 2007, 26(1):8-10
[3] 黄海琴, 谢光远, 王杏, 等. ZrO2基电化学NOx传感器非活化电极浆料的研究[J]. 武汉科技大学学报, 2012, 35(1):41-43
[4] ZHUIYKOV S, MIURA N. High-temperature NOx sensors using zirconia solid electrolyte and zinc-family oxide sensing electrode[J]. Solid StateIonics, 2002, 152-153(EXI-EX10):801-807
[5] MIURA N, RAISEN T, LU G. Highly selective CO sensor using stabilized and a couple of oxide electrodes[J]. Sensors and Actuators B:Chemical, 1998, 47(1-3):84-91
[6] REILLY S A O, DAUNERT S, BACHAS L G. Nitrogen oxide gas sensor based on a nitrite-selective electrode[J]. Sens and Actuators B, 1991:12-15
[7] 罗志安, 肖建中, 夏风, 等. 平板式二氧化锆氧传感器的研究进展[J]. 传感器技术, 2004, 23(8):4-8
[8] 王务林, 冯长根, 赵航, 等. 一种汽车用氧传感器的研制[J]. 机械工程学报, 2003, 35(10):152-155
[9] 唐玲, 李乐. 电极极化及其对NOx传感器剩余氧气浓度的影响[J]. 安庆师范学院学报, 2007, 13(4):37-41
[10] HORISAKA S, LEE S J. NOx sensor:US 2009/0242401 A1[P]. 2009-10-01.
[11] BAIER G, SCHULE V, VOGEL A. Non-Nernstian zirconia sensors for combustion control[J]. Appl. Phys. A:Mater. Sci. Process, 1993(57):51-56
[12] FUJITA H, SHINDO H. Gas sensor, NOx sensor and method of manufacturing gas sensor:US 2009/0242400 A1[P]. 2009-10-01.
[13] NAKASONE O, SASAKI Y. Method of correcting output of NOx sensor:US 2008/0237064 A1[P]. 2008-10-02.
[14] 赵芃. 宽域氧传感器结构与性能相关性研究[D]. 武汉:武汉科技大学2017.
[15] 邓琴琴, 杨旭东. 温度对多孔建材中VOC扩散系数的影响研究[J]. 建筑科学, 2011, 27(6):68-69
